Easy. You add the *.mov file in the main window. The program reads the file and the video presents itself inside the converter.
Look inside the box containing the video and click the icon at the right side to choose your desired export media file. At the bottom of the list, inside "common video" there is "TS" to select. You do this and start the conversion.
There is also "DVD" conversion to select as output witch might be better than "TS".